WOW64 related,
When Windows changed to 64-bit, the system folder name "System32" was kept the same. (The name is 32, but it is a 64-bit system folder used by 64-bit applications)
When a 32-bit application accesses the system folder in 64-bit Windows, it is redirected to the 'SysWOW64' folder, not System32 (the system folder for 32-bit applications in 64-bit Windows is \Windows\SysWOW64).